Genesis of chlorine and sulphur in fumarolic emissions at Vulcano Island (Italy): assessment of pH and redox conditions in the hydrothermal system     

V. Di Liberto  P. M. Nuccio  A. Paonita   《Journal of Volcanology and Geothermal Research》2002,116(1-2)

Chlorine- and sulphur-bearing compounds in fumarole discharges of the La Fossa crater at Vulcano Island (Italy) can be modelled by a mixing process between magmatic gases and vapour from a boiling hydrothermal system. This allows estimating the compounds in both endmembers. Magma degassing cannot explain the time variation of sulphur and HCl concentrations in the deep endmember, which are more probably linked to reactions of solid phases at depth, before mixing with the hydrothermal vapours. Based on the P–T conditions and speciation of the boiling hydrothermal system below La Fossa, the HCl and S_tot contents in the hydrothermal vapours were used to compute the redox conditions and pH of the aqueous solution. The results suggest that the haematite–magnetite buffer controls the hydrothermal fO₂ values, while the pH has increased since the end of the 1970s. The main processes affecting pH values may be linked to Na–Ca exchanges between evolved seawater, feeding the boiling hydrothermal system, and local rocks. While Na is removed from water, calcium enters the solution, undergoes hydrolysis and produces HCl, lowering the pH of the water. The increasing water–rock ratio within the hydrothermal system lowers the Ca availability, so the aqueous solution becomes less acidic. Seawater flowing towards the boiling hydrothermal brine dissolves a large quantity of pyrite along its path. In the boiling hydrothermal system, dissolved sulphur precipitates as pyrite and anhydrite, and becomes partitioned in vapour phase as H₂S and SO₂. These results are in agreement with the paragenesis of hydrothermal alteration minerals recovered in drilled wells at Vulcano and are also in agreement with the isotopic composition of sulphur emitted by the crater fumaroles.  相似文献   

3D shear-wave velocity structure of the Eifel plume, Germany     

Matthias KeyserJoachim R.R. Ritter  Michael Jordan 《Earth and Planetary Science Letters》2002,203(1):59-82

The Quaternary Eifel volcanic fields, situated on the Rhenish Massif in Germany, are the focus of a major interdisciplinary project. The aim is a detailed study of the crustal and mantle structure of the intraplate volcanic fields and their deep origin. Recent results from a teleseismic P-wave tomography study reveal a deep low-velocity structure which we infer to be a plume in the upper mantle underneath the volcanic area [J.R.R. Ritter et al., Earth Planet. Sci. Lett. 186 (2001) 7-14]. Here we present a travel-time investigation of 5038 teleseismic shear-wave arrivals in the same region. First, the transverse (T) and radial (R) component travel-time residuals are treated separately to identify possible effects of seismic anisotropy. A comparison of 2044 T- and 2994 R-component residuals demonstrates that anisotropy does not cause any first-order travel-time effects. The data sets reveal a deep-seated low-velocity anomaly beneath the volcanic region, causing a delay for teleseismic shear waves of about 3 s. Using 3773 combined R- and T-component residuals, an isotropic non-linear inversion is calculated. The tomographic images reveal a prominent S-wave velocity reduction in the upper mantle underneath the Eifel region. The anomaly extends down to at least 400 km depth. The velocity contrast to the surrounding mantle is depth-dependent (from −5% at 31-100 km depth to at least −1% at 400 km depth). At about 170-240 km depth the anomaly is nearly absent. The resolution of the data is sufficient to recover the described features, however the anomaly in the lower asthenosphere is underestimated due to smearing and damping. The main anomaly is similar to the P-wave model except the latter lacks the ‘hole’ near 200 km depth, and both are consistent with an upper mantle plume structure. For plausible anhydrous plume material in the uppermost 100 km of the mantle, an excess temperature as great as 200-300 K is estimated from the seismic anomaly. However, 1% partial melt reduces the required temperature anomaly to about 100 K. The temperature anomaly associated with the deeper part of the plume (250 to about 450 km depth) is at least 70 K. However, this estimate is quite uncertain, because the amplitude of the shear-wave anomaly may be larger than the modelled one. Another possibility is water in the upwelling material. The gap at 170-240 km depth could arise from an increase of the shear modulus caused by dehydration processes which would not affect P-wave velocities as much. An interaction of temperature and compositional variations, including melt and possibly water, makes it difficult to differentiate quantitatively between the causes of the deep-seated low-velocity anomaly.  相似文献   

Isotope variations in a Sierra Nevada snowpack and their relation to meltwater     

Padinare V. Unnikrishna  Jeffrey J. McDonnell  Carol Kendall   《Journal of Hydrology》2002,260(1-4):38-57

Isotopic variations in melting snow are poorly understood. We made weekly measurements at the Central Sierra Snow Laboratory, California, of snow temperature, density, water equivalent and liquid water volume to examine how physical changes within the snowpack govern meltwater δ¹⁸O. Snowpack samples were extracted at 0.1 m intervals from ground level to the top of the snowpack profile between December 1991 and April 1992. Approximately 800 mm of precipitation fell during the study period with δ¹⁸O values between −21.35 and −4.25‰. Corresponding snowpack δ¹⁸O ranged from −22.25 to −6.25‰. The coefficient of variation of δ¹⁸O in snowpack levels decreased from −0.37 to −0.07 from winter to spring, indicating isotopic snowpack homogenization. Meltwater δ¹⁸O ranged from −15.30 to −8.05‰, with variations of up to 2.95‰ observed within a single snowmelt episode, highlighting the need for frequent sampling. Early snowmelt originated in the lower snowpack with higher δ¹⁸O through ground heat flux and rainfall. After the snowpack became isothermal, infiltrating snowmelt displaced the higher δ¹⁸O liquid in the lower snowpack through a piston flow process. Fractionation analysis using a two-component mixing model on the isothermal snowpack indicated that δ¹⁸O in the initial and final half of major snowmelt was 1.30‰ lower and 1.45‰ higher, respectively, than the value from simple mixing. Mean snowpack δ¹⁸O on individual profiling days showed a steady increase from −15.15 to −12.05‰ due to removal of lower δ¹⁸O snowmelt and addition of higher δ¹⁸O rainfall. Results suggest that direct sampling of snowmelt and snow cores should be undertaken to quantify tracer input compositions adequately. The snowmelt sequence also suggests that regimes of early lower δ¹⁸O and later higher δ¹⁸O melt may be modeled and used in catchment tracing studies.  相似文献   

上海数字强震观测网     

徐永林  周生良  熊里军  火恩杰  张奕麟  王炜 《地震地磁观测与研究》2002,23(6):37-43

上海市数字强震观测网是我国第1个具有一定规模的数字强震观测网，是上海市“九五”期间建设完成的，它由3部分组成；地面观测网，结构观测网和深井强震观测系统，每一部分都有不同的功能和目的，本文详细介绍该强震网的整个概况。功能及取得的部分观测成果。  相似文献   

青藏高原土壤水热分布特征及冻融过程在季节转换中的作用   总被引：21，自引：0，他引：21  

杨梅学  姚檀栋  何元庆 《山地学报》2002,20(5):553-558

利用GAME-Tibet期间所取得的高分辩率土壤温度和含水量资料，对青藏高原（主要是藏北高原）土壤水热分布特征及冻融过程在季节转换中的作用进行了分析。指出藏北高原4cm学深处土壤在10月份开始冻结，次年4-5月份开始消融，冻结持续时间长达5-7个月。冻结过程有利于土壤维持其水分，因此，在刚刚开始消融时土壤含水量仍然很高。从而为夏季风爆发前土壤通过蒸发向大气提供水分打下了基础。指出土壤冻融过程可能在高原季节转换中起着重要作用。  相似文献   

Identification of geomorphic process units in Kärkevagge, northern Sweden, by remote sensing and digital terrain analysis     

Annett Bartsch  Martin Gude  Christer Jonasson  & Dieter Scherer 《Geografiska Annaler: Series A, Physical Geography》2002,84(3-4):171-178

Sediment transport processes in the Kärkevagge are investigated concerning their spatial and temporal characteristics due to long–term monitoring. Within this study remote sensing techniques and GIS modelling in connection with geomorphic mapping are applied for identification and characterization of geomorphic process units. Relationships between geomorphometric parameters and slope processes like solifluction, talus creep and rockfall have been analysed. Multitemporal Landsat–TM5 scenes are used as source for landcover characteristics (Normalized Difference Vegetation Index) after preprocessing involving orthorectification and topographic normalization in order to remove possible terrain–induced effects. Additionally, a digital elevation model with a resolution of 20 m for the Kärkevagge catchment is developed and parameters like slope gradient, slope aspect and profile curvature are extracted as input for the analysis of the sediment transport system. The combination of landcover information, geomorphometrical and topological features allows the definition of areas for single process activities. They show specific sediment displacement characteristics depending on material conditions, topological and geometrical features. Geomorphic process units, which show a homogenous composition, are extracted from these available layers.  相似文献   

Vegetation as a tool in the characterisation of geomorphological forms and processes: an example from the Abisko Mountains     

Anna Koz&#;owska  & Zofia R&#;czkowska 《Geografiska Annaler: Series A, Physical Geography》2002,84(3-4):233-244

  相似文献   

Study of weathering processes developed on old piedmont surfaces in Western Spain: new contributions to the interpretation of the “Raña” profiles     

E. Molina Ballesteros  M. Cantano Martín   《Geomorphology》2002,42(3-4)

The Hercynian basement of the Iberian Peninsula was uplifted by the Alpine orogeny during the Tertiary. It gave rise to a set of block mountains and tectonic grabens, one of which is the Ciudad Rodrigo Basin. It is located in Western Spain and forms a westward extension of the great Tertiary Duero Basin. The sediments filling this graben are of continental origin, their ages ranging from Palaeogene to Quaternary. Morphologically, the southern part of this basin forms a set of piedmont surfaces (the “Raña” surfaces) appearing above the terrace system of the present rivers. This paper examines the weathering processes developed over these old piedmont surfaces using micromorphological, XR diffraction, scanning electron microscopy (SEM) and microporosity techniques.The Raña sediments are rich in quartzite pebbles and gravel within a clayey matrix. Once deposited, these materials underwent important in situ weathering processes under somewhat hydromorphic conditions, of which hydrolysis, ferrolysis and xerolysis were the most important. All these processes gave rise to: (1) transformation of most of the clasts of shists and slates into a matrix causing the destruction of the original sedimentary structures and a relative concentration of the resistant lithologies (quartzites and quartz); (2) important changes in the clay fraction, leading to a predominance of kaolinite in the upper levels of the profiles, (3) release of elements from primary minerals, Fe being one of the most important, and (4) redistribution of matter, mainly clay and Fe oxyhydroxides, within the profiles.The coexistence of seasonal periods with pF higher than 4.2 repeated over a long time, together with poor internal and external drainage conditions, are the cause of the special features displayed by Raña deposits.  相似文献   

The rate of grain release by pore-ice sublimation in cold-aeolian environments   总被引：1，自引：0，他引：1  

Deanna van Dijk  Jane Law 《Geografiska Annaler: Series A, Physical Geography》2003,85(1):99-113

Pore‐ice sublimation is a prerequisite for aeolian activity in cold environments where surface sediments hold significant amounts of frozen water. Few quantitative studies have defined the rate of grain release from cemented surfaces by pore‐ice sublimation. In 1996–1997, controlled field experiments at Presqu'ile Beach, Ontario, were implemented to measure sediment release from frozen surfaces. The release rates were compared to the local wind regime, ambient temperature and humidity. In additional field experiments, the effect of sediment water content on grain release by sublimation was examined. From the experimental results, an equation which predicts grain release based on local wind speed, ground temperature, humidity, and surface water content is proposed. Predicted release rates show reasonable agreement with natural deflation measured on the beach at Presqu'ile Provincial Park.  相似文献   

Dynamic processes of a simple linear dune—a study in the Taklimakan Sand Sea, China   总被引：1，自引：0，他引：1  

Xunming Wang  Zhibao Dong  Jianjun Qu  Jiawu Zhang  Aiguo Zhao 《Geomorphology》2003,52(3-4):233-241

Samples of dune sands, surveys of the morphology and field measurements of wind velocity and direction of a simple linear dune in Taklimakan Sand Sea show that the airflow and sand flux vary with the change of wind direction on the dune surface. Decrease of the airflow stress on the lee flank does not result in much decrease of the sand flux because of the low threshold shear velocities and the airflow conditions. There are no significant relations between the sand flux on the lee flank and the angle of incidence of the airflow. The low threshold shear velocities and the maintenance of the sand flux at the lee flank are the main mechanisms keeping the linear shape of the dunes. Measurements of the sand flux shows that it reaches a maximum on the crest of the dune. The grain size of the transported sands has some differences compared to that of the dune surface. The sands transported are finer than that on the dune surface, but better sorted under the influence of the medium to low wind activity. The field experiment results exhibit that it is possible for the dunes to be shaped as linear dunes during the processes of accumulation and elongation.  相似文献